
½üÈÕ£¬¹ú¼ÒÉúÎïҽѧ²ÄÁϹ¤³Ì¼¼ÊõÑо¿ÖÐÐÄ/Ô×ÓÓë·Ö×ÓÎïÀíËùÓàÌÊÚÍŶӳ¤´ïÎåÄêµÄ¹ØÓÚ¶þÔªZnE»ÃÊýÍŴص½CdE»ÃÊýÍŴصÄÊÒÎÂÑôÀë×Ó½»»»µÄÑо¿¹¤×÷£¬ÔÚ»¯Ñ§ÁìÓòȨÍþÆÚ¿¯J. Am. Chem. SocÔÓÖ¾µÃµ½·¢±í£¬ÌâĿΪ¡°Transformations of Magic-Size Clusters via Precursor Compound Cation Exchange at Room Temperature¡±¡£ÂÛÎĵÚÒ»×÷ÕßΪ¹ú¼ÒÉúÎïҽѧ²ÄÁϹ¤³Ì¼¼ÊõÑо¿ÖÐÐIJ©Ê¿ÉúºÎÀö£¬ÓàÌÊÚºÍèﳬȻ²©Ê¿ÎªÂÛÎĹ²Í¬Í¨Ñ¶×÷Õß¡£ÀÖÓã×ãÇòϵÂÛÎĵÚÒ»Íê³Éµ¥Î»¡£

¸ÃÑо¿»ùÓÚÓàÌÊÚÍŶÓÌá³öµÄÔ´´ÐÔÀíÂÛÄ£ÐÍ¡°ÓàÊÏ˫·¾¶Ä£ÐÍ¡±£¨Nat. Commun. 2017, 8, 15467£»J. Phys. Chem. Lett. 2019, 10, 6399?6408£©ºÍ¡°ÓàÊ϶þ²½ºÏ³É·¨¡±£¨Chem. Mater. 2017, 29, 5727?5735£©£¬¸ÃÑо¿Ìá³öZnE MSCs£¨Magic-Size Clusters£¬»ÃÊýÍÅ´Ø£©ÏÈÒì¹¹»¯ÎªZnE PCs£¨Precursor Compounds£¬Ç°Çý»¯ºÏÎ£¬ÔÙÓëCd(OA)2¾ÊÒÎÂÏÂÑôÀë×Ó½»»»·´Ó¦¶øÉú³ÉCdE PCs£¬½ø¶øÔÙÒì¹¹»¯Éú³ÉCdE MSCsµÄÈý²½ÖèµÄÄÉÃ׺ϳɻ¯Ñ§·´Ó¦¡£ZnE MSCµ½CdE MSCµÄÊÒÎÂÑôÀë×Ó½»»»£¬½øÒ»²½Ö§³ÖÁË¡°ÓàÊÏ˫·¾¶Ä£ÐÍ¡±£¬Ö§³ÅÁËÍŶӽüÆÚÌá³öµÄMSCsÖдæÔÚPCsÇÒMSCsºÍPCs¿É·¢ÉúÒì¹¹»¯·´Ó¦¶øÏ໥ת»¯µÄиÅÄ½ÒʾÁËME PC/MSC(M = Zn, Cd)ÖÐÒõÀë×ÓEÊýÁ¿ÊغãºÍ¼Ü¹¹Êغ㣬²ûÃ÷ÁËMS PC/MSC¾ßÓÐÏàËÆµÄ»¯Ñ§¼ÆÁ¿£¬MSe PC/MSC (M = Zn, Cd) Ò²¾ßÓÐÏàËÆµÄ»¯Ñ§¼ÆÁ¿£¬Îª¿ÆÑÐÈËÔ±ÉîÈëÀí½âÖ±½ÓºÏ³ÉPC/MSC¼°Á¿×ÓµãµÄ·´Ó¦»úÀíÌṩÁ˹ؼüÐÔÖ¤¾Ý£ºÊÇÒõÀë×ÓE·´Ó¦Îï/ǰÇý»¯ºÏÎ¶ø²»ÊÇÑôÀë×ÓM·´Ó¦Îï/ǰÇý»¯ºÏÎ¶¨Á¿µØÖ÷µ¼×ÅME QDÓÕµ¼ÆÚÖÐPC¡°ÏÈ·¢Éú×Ô×é×°·´Ó¦£¬ÔÙÉú³ÉM-E¹²¼Û¼ü¡±µÄ·´Ó¦¹ý³Ì¡£
ÓàÌÊÚÍŶÓDZÐĽºÌå°ëµ¼ÌåÁ¿×ÓµãÁìÓò»ù´¡Ñо¿£¬×¨×¢ÓÚ̽¾¿ºÏ³ÉÁ¿×ÓµãµÄ·´Ó¦»úÀíºÍ·´Ó¦Â·¾¶£¬ÉîÈë̽Ë÷ÄÉÃ׺ϳɻ¯Ñ§ºÍ´«Í³»¯Ñ§£¨ÎÞ»ú/Óлú»¯Ñ§£©µÄ±¾ÖÊÇø±ð²¢ÖÂÁ¦ÓÚΪÄÉÃ׺ϳɻ¯Ñ§µÄѧ¿Æ½¨Éè·¢Õ¹µì¶¨ÀíÂÛ»ù´¡£¬ÍŶӹ¤×÷ÔøÈý¶È»ñµÃѧУÄê¶ÈÊ®´ó»ù´¡Ñо¿ÈÙÓþ£¨2018¡¢2019¡¢2021Ä꣩¡£×Ô¡°ÓàÊÏ˫·¾¶Ä£ÐÍ¡±ºÍ¡°ÓàÊ϶þ²½ºÏ³É·¨¡±Ìá³öÒÔÀ´£¬ÍŶÓÎ§ÈÆPCÀۼƷ¢±íÂÛÎÄ40ÓàÆª£¬Öð²½ÍêÕû¹¹½¨³öÁ˰üÀ¨Òì¹¹»¯·´Ó¦£¨Nat. Commun. 2018, 9, 2499; 2020, 11, 4199£©¡¢Öû»·´Ó¦£¨Nat. Commun. 2019, 10, 1674; Angew. 2020, 59, 16943; 2022, e202114551£»e202205784£©¡¢·Ö½â·´Ó¦£¨Angew. 2020, 59, 12013; 2022, e202209615£©¡¢¼Ó³É·´Ó¦£¨Angew. 2021, 60, 20358£©¼°ÑôÀë×Ó½»»»·´Ó¦£¨JACS 2022, 144, 19060£©µÈÔÚÄڵŦÄÜÄÉÃײÄÁϺϳɷ´Ó¦»úÀíÄ£ÐÍÌåϵ¡£ÉÏÊöÀíÂÛÄ£Ðͼ°ÊµÑé³É¹ûµÄ²»¶ÏÀۼƣ¬ÓÐÍû°ïÖúÄÉÃ׺ϳɻ¯Ñ§´ÓÒÀ¿¿¡°¹¤½³ÊÖÒÕ¡±µÄ¾Ñé½×¶ÎÕæÕýÉÏÉý³ÉΪһÃŶÀÁ¢Ñ§¿Æ£¬Íƶ¯Ñ§¿ÆÏà¹Ø¸ÅÄîÌåϵÖ𲽿ÆÑ§»¯¾«×¼»¯·¢Õ¹£¬ÊµÏÖѧ¿Æ¡°´Ó0µ½1¡±µÄÖØ´óÍ»ÆÆ¡£
¹ú¼Ê²ÄÁ϶¥¼¶ÆÚ¿¯Nature Reviews Materials (2022, 7, 596-596£©¶ÔÍŶӵÄPCÑо¿¹¤×÷½øÐйýרÌⱨµÀ¡£Öйú¿ÆÑ§ÔºÔºÊ¿ÁõÖÒ·¶ÔÚ¡¶ÎïÀí»¯Ñ§Ñ§±¨¡·£¨Acta Phys. -Chim. Sin. 2019, 35, 451¨C452£»2020, 36, 2005052£»2021, 37, 2008014£©Ò²¸ß¶ÈÆÀ¼ÛÁËÍŶӵÄϵÁпÆÑгɹû£¬¶Ô¡°ÓàÊÏ˫·¾¶Ä£ÐÍ¡±µÄ¿ÆÑ§ÀíÂÛ¼ÛÖµ¡¢Í»ÆÆÐÔºÍÇ°ÑØÐԸ߶ȿ϶¨£¬²¢³ä·ÖÈϿɡ°ÓàÊ϶þ²½ºÏ³É·¨¡±¶ÔһϵÁжþÔªII-VI×å°ëµ¼ÌåMSCµÄµÍθßЧºÏ³ÉµÄÆÕÊÊÐÔÒÔ¼°¸Ã·½·¨¿Ë·þĿǰ½ºÌå°ëµ¼ÌåÁ¿×ÓµãºÏ³ÉÖдæÔÚµÄÖØ¸´ÐԲ²úÂʵ͵ÈÎÊÌâµÄÓ¦ÓÃǰ¾°¡£
ÂÛÎÄÁ´½Ó£ºhttps://pubs.acs.org/doi/10.1021/jacs.2c07972
ÐÂÎÅÀ´Ô´£ºhttps://www.scu.edu.cn/info/1207/23330.htm